Monovalent chiral-at-copper complexes: halide-controlled diastereoselectivity
نویسندگان
چکیده
منابع مشابه
Monovalent chiral-at-copper complexes: halide-controlled diastereoselectivity.
An unusual example of diastereoselectivity has been observed in Cu(κ(3)-P,C,P'-1)X complexes where 1 is an asymmetric tridentate ligand containing a bicyclic NHC framework and X is a halide. When X is Cl(-), the S(Cu) isomer is formed selectively whereas when X = I(-) the R(Cu) diastereomer is preferred.
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ژورنال
عنوان ژورنال: Chemical Communications
سال: 2012
ISSN: 1359-7345,1364-548X
DOI: 10.1039/c2cc33036a